علوم و فناوری نساجی و پوشاک

علوم و فناوری نساجی و پوشاک

بهینه سازی خواص فیزیکی و اصلاح سطحی پارچه پلی استرپوشش داده شده با گرافن اکساید/پلی آنیلین با استفاده از آنالیز آماری طرح مرکب مرکزی(CCD)

نوع مقاله : مقاله پژوهشی

نویسندگان
دانشکده مهندسی نساجی، پوشاک و مد، واحد قائم شهر، دانشگاه آزاد اسلامی، قائم شهر، ایران. ص پ 163
چکیده
هدف از این کار ، کسب بهینه­ترین حالت خصوصیات فیزیکی و موفولوژی سطحی پارچه پلی­استر عمل­آوری شده با گرافن­اکساید/پلی­آنیلین می­باشد و این پوشش­دهی چه تغییراتی در ساختار فیزیکی پارچه پلی­استر می­تواند ایجاد نماید. بدین منظور ابتدا پیش عملیات قلیایی و تشعشع مایکرویو جهت ایجاد اصلاح و تخریب سطحی قبل از عملیات پوشش­دهی انجام گرفت. سپس عملیات پوشش­دهی با گرافن­اکساید با درصد های مختلف ( 1% و 5%) و سپس پلی­آنیلین با درصدهای مختلف (1%، 5% و7%) روی سطح پارچه پلی­استر انجام گرفت که تصاویر تغییرات موفولوژی سطحی و پوشش­دهی پارچه با استفاده از میکروسکوپ الکترونی انعکاسی(SEM) نشان داده شد. با توجه به نتایج پیک­های کسب شده در FTIR، گروه­هایC-O وC=O مشاهده شده درمحدوده cm-11293و1735برای نمونه شاهد در اثر واکنشهای قلیایی، آغشته سازی با گرافن و آنیلین مشخص می­گردد که این گروه تحت تاثیر واکنش قرار گرفته و تغییرات ایجاد نموده است که این تغییرات تا طول موج cm-11236 و cm-11639 برای گروه عاملی کربونیل رخداده است که نشان از واکنش پذیری این گروه­ها درساختار پلی­استر می باشد. از طرفی خصوصیات فیزیکی پارچه نیز مورد ارزیابی قرار گرفت که بیشترین مقدار تنش پارگی مربوط نمونه عمل آوری شده با 1% گرافن و 7% پلی­آنیلین مشاهده گردید. در پایان بهینه ترین حالت پوشش­دهی گرافن­اکساید/پلی­آنیلین با استفاده از نرم افزار Design Expert 11 و روش آماری طرح مرکب مرکزی با میزان 02/2 درصد برای گرافن­اکساید و 29/4 درصد برای پلی­آنیلین جهت کسب درصد تنش پارگی و مدول یانگ مطلوب بدست آمد.
کلیدواژه‌ها
موضوعات

عنوان مقاله English

Optimization of physical properties and surface modification of polyester fabric coated with graphene oxide/polyaniline using statistical analysis of central composite design(CCD)

نویسندگان English

Samereh Rezaei
Siavash Afrashteh
Pieman Valipour
Department of Textile Engineering, Apparel, and Fashion, QaS.C.,Islamic Azad University, Qaem Shahr, IRAN, P.O.Box 163
چکیده English

The aim of this work is to obtain the most optimal physical properties and surface morphology of polyester fabric treated with GO/PAn and what changes this coating can cause in the physical structure of polyester fabric. For this purpose, first, alkaline pre-treatment and microwave radiation were performed to modify and destroy the surface before the coating operation. Then, the coating operation with GO with different percentages (1% and 5%) and then PAn with different percentages (1%, 5% and 7%) was performed on the surface of the polyester fabric, and the changes in surface morphology and fabric coating were shown using a scanning electron microscope (SEM). According to the results of the peaks obtained in FTIR, the C-O and C=O groups observed in the range of 1293 and 1735 for the control sample due to alkaline reactions, impregnation with graphene and aniline, it is clear that this group has been affected by the reaction and has caused changes, and these changes have occurred up to the wavelength of 1236 and 1639 cm-1 for the carbonyl group, which indicates the reactivity of these groups in the polyester structure. On the other hand, the physical properties of the fabric were also evaluated, and the highest amount of tearing stress was observed for the sample treated with 1% GO and 7% PAn. Finally, the most optimal GO/PAn coating wasdetermined using Design-Expert 11 software and the Central Composite Design statistical methodwith a percentage of 2.02 percent for GO and 4.29 percent for PAn to obtain the desired tearing stress and Young's modulus.

کلیدواژه‌ها English

Optimization
polyester fabric
Microwave Irradiation
Graphene Oxide (GO)
Polyaniline (PAn)
Design Expert11 Software
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  • تاریخ دریافت 24 اردیبهشت 1405
  • تاریخ بازنگری 01 مرداد 1405
  • تاریخ پذیرش 02 مرداد 1405