علوم و فناوری نساجی و پوشاک

علوم و فناوری نساجی و پوشاک

سلول خورشیدی منسوج پروسکایتی حاوی Cu2ZnSnS4

نوع مقاله : مقاله پژوهشی

نویسندگان
1 'گروه مهندسی شیمی دانشکده فنی ، دانشگاه گیلان، رشت، ایران
2 گروه مهندسی شیمی نساجی و علوم الیاف، دانشکده فنی ،،دانشگاه گیلان ، رشت ، گیلان ، ایران
3 انستیتو انرژی خورشیدی آلی و هیبریدی ف گروه مهدسی الکترونیک، دانشگاه پلی تکنیک رم، رم ، ایتالیا
چکیده
مقاله حاضر بر توسعه سلول‌های خورشیدی منسوج پروسکایتی با قابلیت انعطاف‌پذیری مکانیکی، ساخت در دمای پایین و مقرون به صرفه بودن متمرکز شده است. پلی اتیلن ترفتالات در مقایسه با سایر بسترهای شفاف مانند پلی اتیلن نفتالات به عنوان یک بستر انتخابی مورد توجه قرار گرفته است؛ زیرا نه تنها از نظر شیمیایی پایدار است، بلکه بسیار ارزان‌تر بوده، که عامل مهمی برای توسعه فناوری فتوولتائیک است. در این تحقیق برای نخستین بار اسپیرو با نانوذرات CZTS به عنوان یک ماده انتقال دهنده حفره غیرآلی در سلول‌های انعطاف‌پذیر مبتنی بر لایه انتقال دهنده الکترون اکسید قلع جایگزین گردید. بهینه‌سازی غلظت نانوذرات CZTS در حلال ایزوپروپانول منجر به بالاترین بازده تبدیل انرژی 4/2% با ولتاژ مدار باز V 0/87، جریان اتصال کوتاه mA/cm2 1/9 و فاکتور پرکنندگی ب1/30% برای غلظت mg/mL 15 و اندازه ذرات 10 نانومتر گردید. عملکرد فتوولتائیکی بهتر این سلول‌ها مربوط به استخراج کارآمدتر حفره و کاهش بازترکیبی حامل‌های بار می‌باشد، که در نتیجه منجر به ایجاد مقاومت انتقال بار کم‌تر در مقایسه با غلظت‌های دیگر می‌گردد. در نهایت، سلول‌های انعطاف‌پذیر حاصل با موفقیت بر روی منسوج تعبیه گردید که نشان‌دهنده قابلیت آن‌ها برای یکپارچه‌سازی با تجهیزات الکترونیک هوشمند قابل حمل و پوشش خواهد بود.
کلیدواژه‌ها

موضوعات


عنوان مقاله English

Perovskite Textile Solar Cells Containing Cu2ZnSnS4

نویسندگان English

Vahid Mottaghitalab 1
Zeynab Skafi 2
leila Mivehi 2
Thomas M Brown 3
1 Chemical Engineering Department, Faculty of Engineering, University of Guilan,, Rasht,, Iran
2 Textile engineering department, Faculty of Engineering, University of Guilan, Rasht, Guilan
3 CHOSE (The Centre for Hybrid and Organic Solar Energy), Department of Electronic Engineering, University of Rome Tor Vergata, Via del Politecnico 1, 00133, Rome, Italy Via del Politecnico 1, 00133, Rome, Italy
چکیده English

Current paper has been focused on development of perovskite textile solar cells with mechanical flexibility, low-temperature manufacturing, and cost-effectiveness. Polyethylene terephthalate (PET) has become the substrate of choice compared to other transparent plastic substrates like polyethylene naphthalate (PEN) because it is not only chemically stable but also much cheaper, as an important factor for the photovoltaics (PV) technology development. Herein, spiro-OMeTAD was substituted with CZTS nanoparticles for the first time as an inorganic hole transporting material in flexible perovskite solar cells based on SnO2 electron transport layer. Trough Optimization of CZTS concentration in IPA, the maximum PCE of 2.4% with open-circuit voltage (VOC) of 0.87 V, short current (JSC) of 9.1 mA/cm2 and fill factor (FF) of 30.1% was achieved at a concentration of 15 mg/mL and particle size of 10 nm. The enhanced PV performance of these cells is related to more efficient hole-extraction and reduced carrier recombination, leading to less transport resistance of hole transport layer compared to other concentrations. Subsequently, the flexible cells were successfully embedded on a textile substrate, indicating cells can be seamlessly integrated with portable and wearable smart electronics.

کلیدواژه‌ها English

Textile
solar cells
.perovskite
CZTS
Inorganic HTL
 
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  • تاریخ دریافت 17 بهمن 1402
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