بررسی رنگپذیری و ایزوترم جذب الیاف جوت پوشش داده شده با نانو نقره و متیل‌متا‌آکریلات با رنگزای متال کمپلکس

نوع مقاله : مقاله پژوهشی

نویسندگان

دانشگاه آزاد اسلامی واحد یادگار امام خمینی (ره) شهرری

چکیده

در این تحقیق ابتدا نانو ذرات نقره روی سطح الیاف جوت به روش سنتز همزمان پوشش داده شد. در این روش، هم سنتز و هم رسوب نانو ذرات نقره روی کالای جوت در یک حمام انجام شد. سپس کالا با رزین متیل‌متا‌آکریلات پوشش داده شدند. تصاویر میکروسکوپ روبشی (SEM) نشان داد که اندازه ذرات نانو نقره حدود 29 تا 230 نانومتر بودند. به کارگیری ذرات نانو  نقره باعث اندکی تغییر رنگ در ظاهر الیاف شد، به طوری که  شاخص سفیدی کاهش و شاخص زردی الیاف افزایش پیدا کرد. تصاویر میکروسکوپ روبشی (SEM) نشان داد که حضور نانو نقره و متیل‌متا‌آکریلات روی سطح الیاف باعث ایجاد نا‌‌‌‌همواری در سطح الیاف می شود. مقادیر بازتابش نور نیز کاهش شاخص درخشندگی الیاف را نشان داد.  مقادیر ضریب همبستگی نشان دادند که جذب رنگزای متال کمپلکس روی الیاف جوت از مدل فروندلیچ تبعیت می کند. نتایج حاصل از آزمایشات ایزوترم جذب نشان داد که هم ظرفیت جذب لیف و هم شدت جذب رنگزای متال کمپلکس در اثر انجام این نوع تکمیل افزایش یافته است. ضمناً الیافی که به این روش تکمیل شده اند ثبات نوری و شستشویی بهتری را در مقایسه با الیاف خام نشان می دهند.

کلیدواژه‌ها

موضوعات


عنوان مقاله [English]

Investigating the dyeability and adsorption isotherm of jute fibers coated with nano silver and methyl methacrylate with metal complex dye

نویسندگان [English]

  • Ali Akbar Zolriasatein
  • Mehrdad Hajilari
  • Salehi Milad
Department of Textile Engineering, College of Technical and Engineering, Yadegar-e-Imam Khomeini (RAH) Shahre-rey Branch, Islamic Azad University, Tehran, Iran
چکیده [English]

In this research, silver nano particles were first coated on the surface of jute fibers through simultaneous synthesis method. In this approach, both the synthesis and deposition of silver nanoparticles on jute were carried out in one bath. Then these treated fibers were coated with methyl methacrylate. Scanning electron microscopy (SEM) micrographs showed that the size of nano silver particles was between 29 and 230 nanometers.The use of nano silver particles caused a slight color change in the appearance of the fibers so that the whiteness index decreased and the yellowness index of the fibers increased. The SEM microgrphs showed that the presence of nano silver and methyl methacrylate on the surface of the fibers causes roughness on the surface of the fibers. The reflection values ​​also showed a decrease in the brightness index of the fibers. The values of correlation coefficient showed that the adsorption of metal complex dye onto jute fibers obeys the Freundlich model. The results of the adsorption isotherm tests showed that both the adsorption capacity and the absorption intensity for the metal complex dyes increased due to this type of finishing. Moreover, these finished fibers showed better light and washing fastness compared to the raw fiber.

کلیدواژه‌ها [English]

  • Jute fibers
  • whiteness index
  • Freundlich adsorption isotherm
  • Langmuir adsorption isotherm
  • light fastness
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