Effect of Ultraviolet Irradiation on Thermodynamic, Kinetic ‎and Adsorption Isotherm of Direct dye onto Cellulose ‎Acetate Fabric

Document Type : Research/ Original/ Regular Article

Authors

Department of Textile Engineering, College of Technical and Engineering, Yadegar-e-Imam Khomeini (RAH) Shahre-rey Branch, Islamic Azad University, Tehran, Iran

Abstract

Cellulose acetate fibers do not inherently have an affinity for direct dyes. One ‎of the methods to create affinity for this type of dye is saponification of ‎cellulose acetate fibers, which converts some acetate groups to hydroxyl ‎groups. However, the alkaline wastewater from saponification is a high ‎concentration alkaline wastewater. Therefore, other techniques should be ‎investigated to create hydrophilic groups on the surface of these fibers. In this ‎research, cellulose acetate fibers were first exposed to ultraviolet radiation and ‎then chemical and dyeing properties were investigated.SEM micrographs ‎showed that UV pretreatment makes fiber surface rough and porous.‎‏ ‏Moreover, FT-IR results showed that acetyl groups decreased after UV ‎treatment. Meanwhile, increasing irradiation time led to an increase in color ‎strength and fastness properties. Thermodynamic parameters showed that UV ‎treated fabric had higher affinity for direct dye in comparison to untreated ‎fabric. Freundlich isotherm was found the best model to describe the ‎adsorption of direct dye onto both untreated and UV treated cellulose acetate ‎fabrics. However, UV treated fabric showed higher adsorption capacity in ‎comparison to untreated fabric.‎

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