Synthesis of SBA-15/ZIF-8 nanocomposite for removal of reactive red 198 from textile waste water

Document Type : Research/ Original/ Regular Article

Authors

1 Department of Chemistry, Qaemshahr Branch, Islamic Azad University, Qaemshahr, Iran

2 Department of textile engineering, Qaemshahr branch, Islamic Azad University, Qaemshahr, Iran

Abstract

One of the water pollutants is dyes that are widely used in the textile industry. The most important dye compound used in the textile industry is reactive dye. In this study, SBA-15/ZIF-8 nanocomposite was synthesized and used for the removal of reactive red 198 from aqueous solution. For approving the synthesized adsorbent structure, BET and transform infra-red spectroscopy (FT-IR) techniques were used. UV−Vis spectrophotometer was used to determine the amount of residual dye in solution. The effect of different experimental parameters such as pH, adsorbent dosage, contact time, initial dye concentration, and temperature on the adsorption were studied. The optimum condition were pH = 2, adsorbent dosage of 0.03 g, and contact time of 90 min at 25 °C. In the studies performed, it was found that with increasing temperature, the amount of adsorption decreased, which represents that the adsorption process of 198 reactive red dye on the synthesized adsorbent SBA-15 / ZIF-8 is exothermic.

Keywords

Main Subjects


 1. Ghaharpour, M., Rashidi, A., Tayebi, H., Adsorption Behavior of Disperse Orange 30 on Polyester Fabric, World Appl.
Sci. J., 14, 1291-1295, 2011
2. Tayebi, H. A., Dalirandeh, Z., Shokuhi Rad, A., Mirabi, A.,
Binaeian, E., Synthesis of polyaniline/Fe3O4 magnetic nanoparticles for removal of reactive red 198 from textile waste
water: kinetic, isotherm, and thermodynamic studies, Desalin Water Treat., 57, 2255-2268, 2016
3. [3] Tayebi, H. A., Using RBF and MLP models in predicting
Reactive Red 198 removal from aqueous solution by SBA-
15/CTAB composite, Desalin Water Treat., 66, 263-273,
2017
4. M. Ghanei, A. Rashidi, H. A. Tayebi, M. E. Yazdanshenas,
H. Rezainejad, Adsorption of acid Blue 25 dye by CPAA
coated on SBA-15 in aqueous solution: A density functional
theory study, Synth. Met., 269, 116568, 2020
5. Zareyee, D., Tayebi, H. A., Javadi, S. H., Preparation of polyaniline/activated carbon composite for removal of reactive
red 198 from aqueous solution, Iran. J. Org. Chem., 4, 799-
802, 2012
6. Javadian, H., Ghorbani, F., Tayebi, H. A., Asl, S. H., Study
of the adsorption of Cd (II) from aqueous solution using zeolite-based geopolymer, synthesized from coal fly ash; kinetic, isotherm and thermodynamic studies, Arab. J. Chem.,
8(6), 837-849, 2015
7. Shabandokht, M., Binaeian, E., Tayebi, H. A., Adsorption of
food dye Acid red 18 onto polyaniline-modified rice husk
composite: isotherm and kinetic analysis, Desalin Water
Treat., 57(57), 27638, 2016
8. Binaeian, E., Tayebi, H. A., Rad, A. S., Payab, M., Surface
modification of mesoporous silicate by tannin for immobilization of TiO2 nanoparticles: Study of photocatalytic performance, Mater. Chem. Phys., 185, 14-23, 2017
9. Binaeian, E., Seghatoleslami, N., Chaichi, M. J., Tayebi, H.
A., Preparation of titanium dioxide nanoparticles supported
on hexagonal mesoporous silicate (HMS) modified by oak
gall tannin and its photocatalytic performance in degradation
of azo dye, Adv Powder Technol., 27(4),1047-1055, 2016
10. Shafiabadi, M., Dashti, A., Tayebi, H. A., Removal of Hg
(II) from aqueous solution using polypyrrole/SBA-15 nanocomposite: Experimental and modeling, Synth. Met., 212,
154-160, 2016
11. Tayebi, H. A., Ghanei, M., Aghajani, K., Zohrevandi, M.,
Modeling of reactive orange 16 dye removal from aqueous
media by mesoporous silica/ crosslinked polymer hybrid using RBF, MLP and GMDH neural network models, J. Mol.
Struct.,1178, 514-523, 2019
12. Mirzaie, M., Rashidi, A., Tayebi, H. A., Yazdanshenas, M.
E., Optimized Removal of Acid Blue 62 from Textile Waste
Water by SBA-15/PAMAM Dendrimer Hybrid Using Response Surface Methodology, J Polym Environ., 26(5),
1831-1843, 2018
13. Aghajani, K., H. A. Tayebi, H. A., Synthesis of SBA-15/
PAni mesoporous composite for adsorption of reactive dye
from aqueous media: RBF and MLP networks predicting
models, Fiber Polym., 18(3), 465-475, 2017
14. Mirzaie, M., Rashidi, A., Tayebi, H. A., Yazdanshenas, M.
E., Removal of Anionic Dye from Aqueous Media by Adsorption onto SBA-15/Polyamidoamine Dendrimer Hybrid:
Adsorption Equilibrium and Kinetics, J. Chem. Eng. Data.,
62(4),1365-1376, 2017
15. Ghorbani, H. R., Hoseinpour Kasgari, A., Production of Nanocomposite Film Based on Epoxy Resin, J. text. sci. technol., 9, 5–16, 2020
16. Abadi, Z, K., Nourbakhsh, S., Montazer, M., Zinc Oxide Nanoparticles Treated Polyester Fabric in Calcium Hydroxide
Media, J. text. sci. technol., 5, 21–30, 2015
17. Nazari, A., Davodi-Roknabadi, A., Structural Equations
Analysis and Design of Polyimide 6,6 Fabrics Multi functional Properties Finished with Silver Nanoparticles and Bu
  tane tetra carboxylic acid using Mediatory Property of Hydrophilicity, J. text. sci. technol., 34, 5–19, 2020
18. Torabinejad, A., Nasirizadeh, N., Yazdanshenas, M. E.,
Tayebi, H. A., Synthesize and characterization of Aminosilane functionalized MCM-41 for removal of anionic dye:
Kinetic and thermodynamic study, Int J Nano Dimens., 7(4),
295-307, 2016
19. Aghajani, K., Tayebi, H. A., Adaptive Neuro-Fuzzy Inference system analysis on adsorption studies of Reactive Red
198 from aqueous solution by SBA-15/CTAB composite,
Spectrochim. Acta A Mol. Biomol. Spectrosc., 171, 439-448,
2017
20. Ghanei, M., Rashidi, A., Tayebi, H. A., Yazdanshenas, M. E.,
Removal of Acid Blue 25 from Aqueous Media by Magnetic-SBA-15/CPAA Super Adsorbent: Adsorption Isotherm,
Kinetic, and Thermodynamic Studies, J. Chem. Eng. Data.,
63(9), 3592-3605, 2018
21. Binaeian, E., Tayebi, H. A., Shokuhi Rad, A., Afrashteh, A.,
Adsorption of acid blue on synthesized polymeric nanocomposites, PPy/MCM-41 and PAni/MCM-41: Isotherm, thermodynamic and kinetic studies, J Macromol Sci A., 55(3),
269-279, 2018
22. Tayebi, H. A., Yazdanshenas, M. E., Rashidi, A., Khajavi,
R., Montazer, M., The Isotherms, Kinetics, and Thermodynamics of Acid Dye on Nylon6 with Different Amounts of
Titania and Fiber Cross Sectional Shape, J Eng Fiber Fabr.,
10(1), 155-167, 2015
23. Mirzaie, M., Rashidi, A., Tayebi, H. A., Yazdanshenas, M.
E., Adsorption of Acid Dyes on Modified Mesoporous SBA-
15: Comparison of Two Dyes, Phys. Chem. Res., 6(3), 565,
2018
24. Tayebi, H. A., Synthesis of polyaniline/nanosilica nanocomposite for removal of reactive orange 16 from aqueous solutions, Iran. J. Org. Chem., 8, 1737-1744, 2016
25. Akbartabar, I., Yazdanshenas, M. E., Tayebi, H. A., Nasirizadeh,
N., Investigation of Acid Blue 62 dye adsorption using SBA-15/
Polyaniline mesoporous nanocomposite: Kinetic and Thermodynamic study, Iran. J. Health Sci., 5, 17-34, 2017